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smart 1000tm ccd diffractometer  (Bruker Corporation)


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    Bruker Corporation smart 1000tm ccd diffractometer
    Smart 1000tm Ccd Diffractometer, supplied by Bruker Corporation, used in various techniques. Bioz Stars score: 90/100, based on 1 PubMed citations. ZERO BIAS - scores, article reviews, protocol conditions and more
    https://www.bioz.com/product/smart+ccd+1000tm+diffractometer/smart+1000tm+ccd+diffractometer/pm19253992-40-19-18
    Average 90 stars, based on 1 article reviews
    smart 1000tm ccd diffractometer - by Bioz Stars, 2026-10
    90/100 stars

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    other:

    Article Title: Ligand effect on the kinetics of hydroperoxochromium(III)-oxochromium(V) transformation and the lifetime of chromium(V).
    Article Snippet: A macrocyclic superoxochromium complex L(H2O)CrOO (L = meso-Me6-[14]aneN4) is generated from LCr(H2O)2 and O2 with kon = (2.80 ± 0.07) × 10 M−1 s−1.. One-electron reduction of L(H2O)CrOO produces a transient hydroperoxo complex that readily undergoes intramolecular conversion to LCr(V), k1 = 1.00 ± 0.01 s−1 in acidic aqueous solutions, and 0.273 ± 0.010 s−1 at pH >7, with an apparent pKa of 5.9.. The decay of LCr(V) in the pH range 1.3–6.2 obeys the rate law, −d[L2Cr(V)]/dt = (0.0080 (± 0.0049) + 8.19 (± 0.13) [H])[LCr(V)].



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